Magnesium

This article is about the chemical element. For the use of magnesium as a medication, see Magnesium (medical use)

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(Mn).

Not to be confused with manganese

Chemical element with atomic number 12 (Mg)

Magnesium is a chemical element; it has symbol Mg and atomic number 12. It is a shiny gray metal having a low density, low melting point and high chemical reactivity. Like the other alkaline earth metals (group 2 of the periodic table) it occurs naturally only in combination with other elements and it almost always has an oxidation state of +2. It reacts readily with air to form a thin passivation coating of magnesium oxide that inhibits further corrosion of the metal. The free metal burns with a brilliant-white light. The metal is obtained mainly by electrolysis of magnesium salts obtained from brine. It is less dense than aluminium and is used primarily as a component in strong and lightweight alloys that contain aluminium.

In the cosmos, magnesium is produced in large, aging stars by the sequential addition of three helium nuclei to a carbon nucleus. When such stars explode as supernovas, much of the magnesium is expelled into the interstellar medium where it may recycle into new star systems. Magnesium is the eighth most abundant element in the Earth's crust[13] and the fourth most common element in the Earth (after iron, oxygen and silicon), making up 13% of the planet's mass and a large fraction of the planet's mantle. It is the third most abundant element dissolved in seawater, after sodium and chlorine.[14]

This element is the eleventh most abundant element by mass in the human body and is essential to all cells and some 300 enzymes.[15] Magnesium ions interact with polyphosphate compounds such as ATP, DNA, and RNA. Hundreds of enzymes require magnesium ions to function. Magnesium compounds are used medicinally as common laxatives and antacids (such as milk of magnesia), and to stabilize abnormal nerve excitation or blood vessel spasm in such conditions as eclampsia.[15]

Characteristics

Physical properties

Elemental magnesium is a gray-white lightweight metal, two-thirds the density of aluminium. Magnesium has the lowest melting (923 K (650 °C)) and the lowest boiling point (1,363 K (1,090 °C)) of all the alkaline earth metals.[16]

Pure polycrystalline magnesium is brittle and easily fractures along shear bands. It becomes much more malleable when alloyed with small amounts of other metals, such as 1% aluminium.[17] The malleability of polycrystalline magnesium can also be significantly improved by reducing its grain size to ca. 1 micron or less.[18]

When finely powdered, magnesium reacts with water to produce hydrogen gas:

Mg(s) + 2 H2O(g) &#; Mg(OH)2(aq) + H2(g) + .6 kJ/mol

However, this reaction is much less dramatic than the reactions of the alkali metals with water, because the magnesium hydroxide builds up on the surface of the magnesium metal and inhibits further reaction.[19]

Chemical properties

Oxidation

The principal property of magnesium metal is its reducing power. One hint is that it tarnishes slightly when exposed to air, although, unlike the heavier alkaline earth metals, an oxygen-free environment is unnecessary for storage because magnesium is protected by a thin layer of oxide that is fairly impermeable and difficult to remove.[20]

Direct reaction of magnesium with air or oxygen at ambient pressure forms only the "normal" oxide MgO. However, this oxide may be combined with hydrogen peroxide to form magnesium peroxide, MgO2, and at low temperature the peroxide may be further reacted with ozone to form magnesium superoxide Mg(O2)2.[21]

Magnesium reacts with water at room temperature, though it reacts much more slowly than calcium, a similar group 2 metal.[20] When submerged in water, hydrogen bubbles form slowly on the surface of the metal; this reaction happens much more rapidly with powdered magnesium.[20] The reaction also occurs faster with higher temperatures (see § Safety precautions). Magnesium's reversible reaction with water can be harnessed to store energy and run a magnesium-based engine. Magnesium also reacts exothermically with most acids such as hydrochloric acid (HCl), producing magnesium chloride and hydrogen gas, similar to the HCl reaction with aluminium, zinc, and many other metals.[22] Although it is difficult to ignite in mass or bulk, magnesium metal will ignite.

Magnesium may also be used as an igniter for thermite, a mixture of aluminium and iron oxide powder that ignites only at a very high temperature.

Organic chemistry

Organomagnesium compounds are widespread in organic chemistry. They are commonly found as Grignard reagents, formed by reaction of magnesium with haloalkanes. Examples of Grignard reagents are phenylmagnesium bromide and ethylmagnesium bromide. The Grignard reagents function as a common nucleophile, attacking the electrophilic group such as the carbon atom that is present within the polar bond of a carbonyl group.

A prominent organomagnesium reagent beyond Grignard reagents is magnesium anthracene, which is used as a source of highly active magnesium. The related butadiene-magnesium adduct serves as a source for the butadiene dianion.

Complexes of dimagnesium(I) have been observed.[23]

Detection in solution

The presence of magnesium ions can be detected by the addition of ammonium chloride, ammonium hydroxide and monosodium phosphate to an aqueous or dilute HCl solution of the salt. The formation of a white precipitate indicates the presence of magnesium ions.

Azo violet dye can also be used, turning deep blue in the presence of an alkaline solution of magnesium salt. The color is due to the adsorption of azo violet by Mg(OH)2.

Forms

Alloys

Magnesium is brittle, and fractures along shear bands when its thickness is reduced by only 10% by cold rolling (top). However, after alloying Mg with 1% Al and 0.1% Ca, its thickness could be reduced by 54% using the same process (bottom).

As of , magnesium alloys consumption was less than one million tonnes per year, compared with 50 million tonnes of aluminium alloys. Their use has been historically limited by the tendency of Mg alloys to corrode,[24] creep at high temperatures, and combust.[25]

Corrosion

In magnesium alloys, the presence of iron, nickel, copper, or cobalt strongly activates corrosion. In more than trace amounts, these metals precipitate as intermetallic compounds, and the precipitate locales function as active cathodic sites that reduce water, causing the loss of magnesium.[25] Controlling the quantity of these metals improves corrosion resistance. Sufficient manganese overcomes the corrosive effects of iron. This requires precise control over composition, increasing costs.[25] Adding a cathodic poison captures atomic hydrogen within the structure of a metal. This prevents the formation of free hydrogen gas, an essential factor of corrosive chemical processes. The addition of about one in three hundred parts arsenic reduces the corrosion rate of magnesium in a salt solution by a factor of nearly ten.[25][26]

High-temperature creep and flammability

Magnesium's tendency to creep (gradually deform) at high temperatures is greatly reduced by alloying with zinc and rare-earth elements.[27] Flammability is significantly reduced by a small amount of calcium in the alloy.[25] By using rare-earth elements, it may be possible to manufacture magnesium alloys that are able to not catch fire at higher temperatures compared to magnesium's liquidus and in some cases potentially pushing it close to magnesium's boiling point.[28]

Compounds

Magnesium forms a variety of compounds important to industry and biology, including magnesium carbonate, magnesium chloride, magnesium citrate, magnesium hydroxide (milk of magnesia), magnesium oxide, magnesium sulfate, and magnesium sulfate heptahydrate (Epsom salts).[29][30]

As recently as Magnesium hydride was under investigation as a way to store hydrogen.[31][32]

Isotopes

Magnesium has three stable isotopes: 24
Mg, 25
Mg and 26
Mg. All are present in significant amounts in nature (see table of isotopes above). About 79% of Mg is 24
Mg. The isotope 28
Mg is radioactive and in the s to s was produced by several nuclear power plants for use in scientific experiments. This isotope has a relatively short half-life (21 hours) and its use was limited by shipping times.

The nuclide 26
Mg has found application in isotopic geology, similar to that of aluminium. 26
Mg is a radiogenic daughter product of 26
Al, which has a half-life of 717,000 years. Excessive quantities of stable 26
Mg have been observed in the Ca-Al-rich inclusions of some carbonaceous chondrite meteorites. This anomalous abundance is attributed to the decay of its parent 26
Al in the inclusions, and researchers conclude that such meteorites were formed in the solar nebula before the 26
Al had decayed. These are among the oldest objects in the Solar System and contain preserved information about its early history.

It is conventional to plot 26
Mg/24
Mg against an Al/Mg ratio. In an isochron dating plot, the Al/Mg ratio plotted is 27
Al/24
Mg. The slope of the isochron has no age significance, but indicates the initial 26
Al/27
Al ratio in the sample at the time when the systems were separated from a common reservoir.

Production

Magnesium sheets and ingots

Occurrence

Magnesium is the eighth-most-abundant element in the Earth's crust by mass and tied in seventh place with iron in molarity.[13] It is found in large deposits of magnesite, dolomite, and other minerals, and in mineral waters, where magnesium ion is soluble.[33]

Although magnesium is found in more than 60 minerals, only dolomite, magnesite, brucite, carnallite, talc, and olivine are of commercial importance.[34]

The Mg2+
cation is the second-most-abundant cation in seawater (about 1&#;8 the mass of sodium ions in a given sample), which makes seawater and sea salt attractive commercial sources for Mg. To extract the magnesium, calcium hydroxide is added to the seawater to precipitate magnesium hydroxide.[35]

MgCl

2

+

Ca(OH)

2

&#;

Mg(OH)

2

+

CaCl

2

Magnesium hydroxide (brucite) is poorly soluble in water and can be collected by filtration. It reacts with hydrochloric acid to magnesium chloride.[36]

Mg(OH)

2

+ 2 HCl &#;

MgCl

2

+ 2

H

2

O

From magnesium chloride, electrolysis produces magnesium.[37]

Production quantities

World production was approximately 1,100 kt in , with the bulk being produced in China (930 kt) and Russia (60 kt).[38] The United States was in the 20th century the major world supplier of this metal, supplying 45% of world production even as recently as . Since the Chinese mastery of the Pidgeon process the US market share is at 7%, with a single US producer left as of : US Magnesium, a Renco Group company located on the shores of the Great Salt Lake.[39]

In September , China took steps to reduce production of magnesium as a result of a government initiative to reduce energy availability for manufacturing industries, leading to a significant price increase.[40]

Pidgeon and Bolzano processes

An Iranian worker tends to the Pidgeon process

The Pidgeon process and the Bolzano process are similar. In both, magnesium oxide is the precursor to magnesium metal. The magnesium oxide is produced as a solid solution with calcium oxide by calcining the mineral dolomite, which is a solid solution of calcium and magnesium carbonates:

CaCO3·MgCO3 &#; MgO·CaO + 2 CO2

Reduced occurs at high temperatures with silicon. Instead of pure silicon, a ferrosilicon alloy is used because it is cheaper. The iron component is innoncuouse. The reaction can be represented by the following simplified equation:[41]

MgO·CaO +Si &#; 2 Mg + Ca2SiO4

The calcium oxide combines with silicon as the oxygen scavenger, yielding the very stable calcium silicate. The Mg/Ca ratio of the precursors can be adjusted by the addition of MgO or CaO.[42]

The Pidgeon and the Bolzano process differ in the details of the heating and the configuration of the reactor. Both generate gaseous Mg that is condensed and collected. The Pidgeon process dominates the worldwide production.[43][44] The Pidgeon method is less technologically complex and because of distillation/vapour deposition conditions, a high purity product is easily achievable.[43]China is almost completely reliant on the silicothermic Pidgeon process.

Dow process

"Dow process (magnesium)" redirects here. For other Dow processes, see Dow process (disambiguation)

Besides the Pigeon process, the second most used process for magnesium production is electrolysis. This is a two step process. The first step is to prepare feedstock containing magnesium chloride and the second step is to dissociate the compound in electrolytic cells as magnesium metal and chlorine gas.[44] The basic reaction is as follows:

MgCl2 &#; Mg(g) + Cl2(g)

The temperatures at which this reaction is operated is between 680 and 750 °C.[44]

The magnesium chloride can be obtained using the Dow process, a process that mixes sea water and dolomite in a flocculator or by dehydration of magnesium chloride brines. The electrolytic cells are partially submerged in a molten salt electrolyte to which the produced magnesium chloride is added in concentrations between 6-18%.[44] This process does have its share of disadvantages including production of harmful chlorine gas and the overall reaction being very energy intensive, creating environmental risks.[45] The Pidgeon process is more advantageous regarding its simplicity, shorter construction period, low power consumption and overall good magnesium quality compared to the electrolysis method.[20]

In the United States, magnesium was once obtained principally with the Dow process in Corpus Christi TX, by electrolysis of fused magnesium chloride from brine and sea water. A saline solution containing Mg2+
ions is first treated with lime (calcium oxide) and the precipitated magnesium hydroxide is collected:

Mg

2+

(aq) +

CaO

(s) +

H

2

O

(l) &#;

Ca

2+

(aq) +

Mg(OH)

2

(s)

The hydroxide is then converted to magnesium chloride by treatment with hydrochloric acid and heating of the product to eliminate water:

Mg(OH)2 + 2 HCl &#; MgCl2 + 2 H2O

The salt is then electrolyzed in the molten state. At the cathode, the Mg2+
ion is reduced by two electrons to magnesium metal:

Mg

2+

+ 2

e

&#;

&#; Mg

At the anode, each pair of Cl&#;
ions is oxidized to chlorine gas, releasing two electrons to complete the circuit:

2

Cl

&#;

&#;

Cl

2

(g) + 2

e

&#;

Carbothermic process

The carbothermic route to magnesium has been recognized as a low energy, yet high productivity path to magnesium extraction. The chemistry is as follows:

The rotary kiln is used for calcination

C + MgO &#; CO + Mg

A disadvantage of this method is that slow cooling the vapour can cause the reaction to quickly revert. To prevent this from happening, the magnesium can be dissolved directly in a suitable metal solvent before reversion starts happening. Rapid quenching of the vapour can also be performed to prevent reversion.[46]

YSZ process

A newer process, solid oxide membrane technology, involves the electrolytic reduction of MgO. At the cathode, Mg2+
ion is reduced by two electrons to magnesium metal. The electrolyte is yttria-stabilized zirconia (YSZ). The anode is a liquid metal. At the YSZ/liquid metal anode O2&#;
is oxidized. A layer of graphite borders the liquid metal anode, and at this interface carbon and oxygen react to form carbon monoxide. When silver is used as the liquid metal anode, there is no reductant carbon or hydrogen needed, and only oxygen gas is evolved at the anode.[47] It was reported in that this method provides a 40% reduction in cost per pound over the electrolytic reduction method.[48]

History

The name magnesium originates from the Greek word for locations related to the tribe of the Magnetes, either a district in Thessaly called Magnesia[49] or Magnesia ad Sipylum, now in Turkey.[50] It is related to magnetite and manganese, which also originated from this area, and required differentiation as separate substances. See manganese for this history.

In , a farmer at Epsom in England attempted to give his cows water from a local well. The cows refused to drink because of the water's bitter taste, but the farmer noticed that the water seemed to heal scratches and rashes. The substance obtained by evaporating the water became known as Epsom salts and its fame spread.[51] It was eventually recognized as hydrated magnesium sulfate, MgSO
4·7&#;H
2O.[52]

The metal itself was first isolated by Sir Humphry Davy in England in . He used electrolysis on a mixture of magnesia and mercuric oxide.[53] Antoine Bussy prepared it in coherent form in . Davy's first suggestion for a name was 'magnium',[53] but the name magnesium is now used in most European languages.[54]

Uses

Magnesium metal

An unusual application of magnesium as an illumination source while wakeskating in

Magnesium is the third-most-commonly-used structural metal, following iron and aluminium.[55] The main applications of magnesium are, in order: aluminium alloys, die-casting (alloyed with zinc),[56] removing sulfur in the production of iron and steel, and the production of titanium in the Kroll process.[57]

Magnesium is used in lightweight materials and alloys. For example, when infused with silicon carbide nanoparticles, it has extremely high specific strength.[58]

Historically, magnesium was one of the main aerospace construction metals and was used for German military aircraft as early as World War I and extensively for German aircraft in World War II. The Germans coined the name "Elektron" for magnesium alloy, a term which is still used today. In the commercial aerospace industry, magnesium was generally restricted to engine-related components, due to fire and corrosion hazards. Magnesium alloy use in aerospace is increasing in the 21st century, driven by the importance of fuel economy.[59] Magnesium alloys can act as replacements for aluminium and steel alloys in structural applications.[60][61]

Rieke et al developed a "general approach for preparing highly reactive metal powders by reducing metal salts in ethereal or hydrocarbon solvents using alkali metals as reducing agents" known to us as the Rieke process.[62] In he told about Rieke-magnesium.[63] Rieke followed this up in with the identification of Rieke metals.[64]

Aircraft

Automotive

The Bugatti Type 57 Aérolithe featured a lightweight body made of Elektron, a trademarked magnesium alloy.

Both AJ62A and AE44 are recent developments in high-temperature low-creep magnesium alloys. The general strategy for such alloys is to form intermetallic precipitates at the grain boundaries, for example by adding mischmetal or calcium.[74]

Electronics

Because of low density and good mechanical and electrical properties, magnesium is used for manufacturing of mobile phones, laptop and tablet computers, cameras, and other electronic components.[75] It was used as a premium feature because of its light weight in some laptops.[76]

Products made of magnesium: firestarter and shavings, sharpener, magnesium ribbon

Other

Magnesium, being readily available and relatively nontoxic, has a variety of uses:

Source of light

When burning in air, magnesium produces a brilliant white light that includes strong ultraviolet wavelengths. Magnesium powder (flash powder) was used for subject illumination in the early days of photography.[77][78] Later, magnesium filament was used in electrically ignited single-use photography flashbulbs. Magnesium powder is used in fireworks and marine flares where a brilliant white light is required. It was also used for various theatrical effects,[79] such as lightning,[80] pistol flashes,[81] and supernatural appearances.[82]

Magnesium is flammable, burning at a temperature of approximately 3,100 °C (3,370 K; 5,610 °F),[83] and the autoignition temperature of magnesium ribbon is approximately 473 °C (746 K; 883 °F).[84]Magnesium's high combustion temperature makes it a useful tool for starting emergency fires. Other uses include flash photography, flares, pyrotechnics, fireworks sparklers, and trick birthday candles. Magnesium is also often used to ignite thermite or other materials that require a high ignition temperature. Magnesium continues to be used as an incendiary element in warfare.[85]

Magnesium firestarter (in left hand), used with a pocket knife and flint to create sparks that ignite the shavings

.

Flame temperatures of magnesium and magnesium alloys can reach 3,100 °C (5,610 °F),[83] although flame height above the burning metal is usually less than 300 mm (12 in).[86] Once ignited, such fires are difficult to extinguish because they resist several substances commonly used to put out fires; combustion continues in nitrogen (forming magnesium nitride), in carbon dioxide (forming magnesium oxide and carbon), and in water (forming magnesium oxide and hydrogen, which also combusts due to heat in the presence of additional oxygen). This property was used in incendiary weapons during the firebombing of cities in World War II, where the only practical civil defense was to smother a burning flare under dry sand to exclude atmosphere from the combustion.

Chemical reagent

In the form of turnings or ribbons, to prepare Grignard reagents, which are useful in organic synthesis.[87]

Other

Compounds

Magnesium compounds, primarily magnesium oxide (MgO), are used as a refractory material in furnace linings for producing iron, steel, nonferrous metals, glass, and cement. Magnesium oxide and other magnesium compounds are also used in the agricultural, chemical, and construction industries. Magnesium oxide from calcination is used as an electrical insulator in fire-resistant cables.[97]

Magnesium reacts with haloalkanes to give Grignard reagents, which are used for a wide variety of organic reactions forming carbon&#;carbon bonds.[98]

Magnesium salts are included in various foods,[99] fertilizers[100] (magnesium is a component of chlorophyll[101]), and microbe culture media.[102]

Magnesium sulfite is used in the manufacture of paper (sulfite process).[103]

Magnesium phosphate is used to fireproof wood used in construction.[104]

Magnesium hexafluorosilicate is used for moth-proofing textiles.[105]

Biological roles

Mechanism of action

The important interaction between phosphate and magnesium ions makes magnesium essential to the basic nucleic acid chemistry of all cells of all known living organisms. More than 300 enzymes require magnesium ions for their catalytic action, including all enzymes using or synthesizing ATP and those that use other nucleotides to synthesize DNA and RNA. The ATP molecule is normally found in a chelate with a magnesium ion.[106]

Nutrition

Diet

Spices, nuts, cereals, cocoa and vegetables are good sources of magnesium.[15] Green leafy vegetables such as spinach are also rich in magnesium.[107]

Dietary recommendations

In the UK, the recommended daily values for magnesium are 300 mg for men and 270 mg for women.[108] In the U.S. the Recommended Dietary Allowances (RDAs) are 400 mg for men ages 19&#;30 and 420 mg for older; for women 310 mg for ages 19&#;30 and 320 mg for older.[109]

Supplementation

Numerous pharmaceutical preparations of magnesium and dietary supplements are available. In two human trials magnesium oxide, one of the most common forms in magnesium dietary supplements because of its high magnesium content per weight, was less bioavailable than magnesium citrate, chloride, lactate or aspartate.[110][111]

Metabolism

An adult body has 22&#;26 grams of magnesium,[15][112] with 60% in the skeleton, 39% intracellular (20% in skeletal muscle), and 1% extracellular.[15] Serum levels are typically 0.7&#;1.0 mmol/L or 1.8&#;2.4 mEq/L. Serum magnesium levels may be normal even when intracellular magnesium is deficient. The mechanisms for maintaining the magnesium level in the serum are varying gastrointestinal absorption and renal excretion. Intracellular magnesium is correlated with intracellular potassium. Increased magnesium lowers calcium[113] and can either prevent hypercalcemia or cause hypocalcemia depending on the initial level.[113] Both low and high protein intake conditions inhibit magnesium absorption, as does the amount of phosphate, phytate, and fat in the gut. Unabsorbed dietary magnesium is excreted in feces; absorbed magnesium is excreted in urine and sweat.[114]

Detection in serum and plasma

Magnesium status may be assessed by measuring serum and erythrocyte magnesium concentrations coupled with urinary and fecal magnesium content, but intravenous magnesium loading tests are more accurate and practical.[115] A retention of 20% or more of the injected amount indicates deficiency.[116] As of , no biomarker has been established for magnesium.[117]

Magnesium concentrations in plasma or serum may be monitored for efficacy and safety in those receiving the drug therapeutically, to confirm the diagnosis in potential poisoning victims, or to assist in the forensic investigation in a case of fatal overdose. The newborn children of mothers who received parenteral magnesium sulfate during labor may exhibit toxicity with normal serum magnesium levels.[118]

Deficiency

Low plasma magnesium (hypomagnesemia) is common: it is found in 2.5&#;15% of the general population.[119] From to , 48 percent of the United States population consumed less magnesium than recommended in the Dietary Reference Intake.[120] Other causes are increased renal or gastrointestinal loss, an increased intracellular shift, and proton-pump inhibitor antacid therapy. Most are asymptomatic, but symptoms referable to neuromuscular, cardiovascular, and metabolic dysfunction may occur.[119] Alcoholism is often associated with magnesium deficiency. Chronically low serum magnesium levels are associated with metabolic syndrome, diabetes mellitus type 2, fasciculation, and hypertension.[121]

Therapy

• Intravenous magnesium is recommended by the ACC/AHA/ESC Guidelines for Management of Patients With Ventricular Arrhythmias and the Prevention of Sudden Cardiac Death for patients with ventricular arrhythmia associated with torsades de pointes who present with long QT syndrome; and for the treatment of patients with digoxin induced arrhythmias.[122]
• Intravenous magnesium sulfate is used for the management of pre-eclampsia and eclampsia.[123][124]
• Hypomagnesemia, including that caused by alcoholism, is reversible by oral or parenteral magnesium administration depending on the degree of deficiency.[125]
• There is limited evidence that magnesium supplementation may play a role in the prevention and treatment of migraine.[126]

Sorted by type of magnesium salt, other therapeutic applications include:

With competitive price and timely delivery, Meishen sincerely hope to be your supplier and partner.

Overdose

Overdose from dietary sources alone is unlikely because excess magnesium in the blood is promptly filtered by the kidneys,[119] and overdose is more likely in the presence of impaired renal function. In spite of this, megadose therapy has caused death in a young child,[128] and severe hypermagnesemia in a woman[129] and a young girl[130] who had healthy kidneys. The most common symptoms of overdose are nausea, vomiting, and diarrhea; other symptoms include hypotension, confusion, slowed heart and respiratory rates, deficiencies of other minerals, coma, cardiac arrhythmia, and death from cardiac arrest.[113]

Function in plants

Plants require magnesium to synthesize chlorophyll, essential for photosynthesis.[131] Magnesium in the center of the porphyrin ring in chlorophyll functions in a manner similar to the iron in the center of the porphyrin ring in heme. Magnesium deficiency in plants causes late-season yellowing between leaf veins,[132] especially in older leaves, and can be corrected by either applying epsom salts (which is rapidly leached), or crushed dolomitic limestone, to the soil.

Safety precautions

Chemical compound

Magnesium block heated with blowtorch to self-combustion, emitting intense white light

Magnesium metal and its alloys can be explosive hazards; they are highly flammable in their pure form when molten or in powder or ribbon form. Burning or molten magnesium reacts violently with water. When working with powdered magnesium, safety glasses with eye protection and UV filters (such as welders use) are employed because burning magnesium produces ultraviolet light that can permanently damage the retina of a human eye.[135]

Magnesium is capable of reducing water and releasing highly flammable hydrogen gas:[136]

Mg(s) + 2

H

2

O

(l) &#;

Mg(OH)

2

(s) +

H

2

(g)

Therefore, water cannot extinguish magnesium fires. The hydrogen gas produced intensifies the fire. Dry sand is an effective smothering agent, but only on relatively level and flat surfaces.

Magnesium reacts with carbon dioxide exothermically to form magnesium oxide and carbon:[137]

2 Mg(s) +

CO

2

(g) &#; 2 MgO(s) + C(s)

Hence, carbon dioxide fuels rather than extinguishes magnesium fires.

Burning magnesium can be quenched by using a Class D dry chemical fire extinguisher, or by covering the fire with sand or magnesium foundry flux to remove its air source.[138]

See also

Notes

1. ^a = 
   25.31

   ×

   10&#;6
   /K, αc = 
   27.03

   ×

   10&#;6
   /K, and αaverage = αV/3 = 
   25.91

   ×

   10&#;6
   /K.[3]

   The thermal expansion is anisotropic : the parameters (at 20 °C) for each crystal axis are α/K, α/K, and α= α/3 =/K.

References

Cited sources

Magnesium at Wikipedia's

at Wikipedia's

sister projects

• Definitions from Wiktionary

  from Wiktionary

• Media from Commons

  from Commons

• Textbooks from Wikibooks

  from Wikibooks

• Resources from Wikiversity

  from Wikiversity

Your body absorbs certain magnesium supplements more easily. Some types may help support specific health issues.

Magnesium is involved in over 300 essential metabolic reactions, including energy production, blood pressure regulation, nerve signal transmission, and muscle contraction (1).

Low magnesium levels may be involved in various health conditions, such as type 2 diabetes, heart disease, osteoporosis, and migraine (2).

Although many whole foods like green leafy vegetables, legumes, nuts, and seeds contain magnesium, up to two-thirds of people in the Western world don&#;t meet their magnesium needs with diet alone (1).

Keep reading to learn the ten various forms of magnesium supplements and their uses.

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1. Magnesium citrate

Magnesium citrate is a form of magnesium that&#;s bound with citric acid.

This acid is found naturally in citrus fruits, giving them their tart, sour flavor (3).

Magnesium citrate is one of the more common magnesium supplement formulations and can be purchased in stores worldwide.

A small study of 14 male participants suggests that this type is among the most bioavailable forms of magnesium, meaning it&#;s more easily absorbed in your digestive tract than other forms (4).

It&#;s typically taken orally to replenish low magnesium levels. Due to its natural laxative effect, it&#;s also sometimes used at higher doses to treat constipation.

It&#;s occasionally marketed as a calming agent to help relieve symptoms associated with depression and anxiety, but more research is needed on these uses (5).

Summary

Magnesium citrate is one of the most popular types of magnesium supplements and easily absorbed by your body. It&#;s mainly used to raise magnesium levels and treat constipation.

2. Magnesium oxide

Magnesium oxide is a salt that combines magnesium and oxygen.

It naturally forms a white, powdery substance and may be sold in powder or capsule form (6).

This type isn&#;t typically used to prevent or treat magnesium deficiencies, as some studies report that it&#;s poorly absorbed by your digestive tract (7).

Instead, people use it more frequently to relieve uncomfortable digestive symptoms, such as heartburn, indigestion, and constipation. Some may also use it to treat and prevent migraine episodes, but more research is needed to confirm that magnesium deficiency can contribute to migraine attacks (8, 9).

Summary

Magnesium oxide may help relieve digestive complaints like heartburn and constipation. Given that the body doesn&#;t absorb it well, it isn&#;t a good choice for those who need to raise their magnesium levels. You may want to consult with a doctor before taking magnesium oxide.

3. Magnesium chloride

Magnesium chloride is a magnesium salt that includes chlorine &#; an unstable element that binds well with other elements, including sodium and magnesium, to form salts.

It&#;s well absorbed in your digestive tract, making it a great multi-purpose supplement. You can use it to treat low magnesium levels (2, 7, 10).

People take magnesium chloride most frequently in capsule or tablet form, but it may also be an ingredient in topical products like lotions and ointments.

Although people use these skin creams to soothe and relax sore muscles, little scientific evidence links them to improved magnesium levels (11).

Summary

Magnesium chloride is easily absorbed orally and used to treat heartburn, constipation, and low magnesium levels. Also, applying it topically may help relieve muscle soreness but not boost your magnesium levels.

4. Magnesium lactate

Magnesium lactate is the salt formed when magnesium binds with lactic acid.

This acid is produced by your muscle and blood cells and is manufactured as a preservative and flavoring agent (12).

Indeed, magnesium lactate is utilized as a food additive to regulate acidity and fortify foods and beverages. It&#;s less popular as an over-the-counter dietary supplement.

Your digestive tract easily absorbs magnesium lactate, which may also be gentler on your digestive system than other types. This may benefit people who need to take large doses of magnesium regularly or don&#;t easily tolerate other forms.

In a study of 28 people with a rare condition that required high doses of magnesium daily, those who took a slow-release tablet of magnesium lactate reported fewer digestive side effects than the control group (13).

Other studies likewise reveal that this form may help treat stress and anxiety, but more research is needed (14).

Summary

Magnesium lactate is effective as a dietary supplement and possibly gentler on your digestive system. It may be more suitable for those who don&#;t tolerate other forms or need to take especially large doses.

5. Magnesium malate

Magnesium malate includes malic acid, which occurs naturally in foods like fruit and wine. This acid has a sour taste and is often added to food to add flavor or acidity.

Research suggests that magnesium malate is very well absorbed in your digestive tract, making it a great option for replenishing your magnesium levels (15).

Some people report that it&#;s gentler on your system and may have a less laxative effect than other types. This may be beneficial, depending on your specific needs.

Magnesium malate is occasionally recommended to treat fibromyalgia and chronic fatigue syndrome symptoms. But while some studies have found there may be benefits, more high quality studies are needed (16).

Summary

Magnesium malate is easily absorbed and may have less of a laxative effect than other forms. It&#;s occasionally recommended for chronic conditions like fibromyalgia, but more scientific evidence is needed to support this.

6. Magnesium taurate

Magnesium taurate contains the amino acid taurine.

Research suggests that adequate intakes of taurine and magnesium play a role in regulating blood sugar. Thus, this form may promote healthy blood sugar levels (17).

Magnesium and taurine also support healthy blood pressure (18, 19).

A animal study revealed that magnesium taurate significantly reduced blood pressure in rats with high levels, indicating that this form may bolster heart health (20).

Keep in mind that more human research is needed.

Summary

Magnesium taurate may be the best form for managing high blood sugar and high blood pressure, though more studies are necessary.

7. Magnesium L-threonate

Magnesium L-threonate is the salt formed from mixing magnesium and threonic acid, a water-soluble substance derived from the metabolic breakdown of vitamin C (21).

This form is easily absorbed. Animal research notes it may be the most effective type for increasing magnesium concentrations in brain cells (22).

Magnesium L-threonate is often used for its potential brain benefits and may help manage certain brain disorders, such as depression, Alzheimer&#;s disease, and age-related memory loss. Nonetheless, more research is needed (23).

Summary

Magnesium L-threonate may support brain health, potentially aiding the treatment of disorders like depression, Alzheimer&#;s, and memory loss. All the same, further studies are necessary.

8. Magnesium sulfate

Magnesium sulfate is formed by combining magnesium, sulfur, and oxygen. It&#;s commonly known as Epsom salt. It&#;s white with a texture similar to that of table salt.

While you can consume it as a treatment for constipation in capsule form or dissolve the powder in water, it has an unpleasant taste. Using too much or using it too often can be dangerous (24).

You can dissolve magnesium sulfate in bathwater to soothe sore, achy muscles and relieve stress. It&#;s also sometimes included in skin care products like lotion or body oil.

Although adequate magnesium levels can play a role in muscle relaxation and stress relief, little evidence suggests that this form is well absorbed through your skin (11).

Summary

Magnesium sulfate, or Epsom salt, is frequently dissolved in water to treat stress and sore muscles. However, more quality research is needed to support its use.

9. Magnesium glycinate

Magnesium glycinate is formed from elemental magnesium and the amino acid glycine.

Your body employs this amino acid in protein construction. It also occurs in many protein-rich foods, such as:

• fish
• meat
• dairy
• legumes

Animal studies suggest that glycine on its own can help improve sleep and treat some inflammatory conditions, including heart disease and diabetes. But more robust studies are needed to further support this (25, 26).

Magnesium glycinate is easily absorbed and may have calming properties. It may help reduce mental health issues, such as: (1)

• anxiety
• depression
• stress
• insomnia

Yet, there is limited scientific evidence on these uses, so more studies are needed.

Summary

Magnesium glycinate is often used for its calming effects to treat anxiety, depression, and insomnia. However, research supporting its efficacy for such conditions is limited.

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10. Magnesium orotate

Magnesium orotate includes orotic acid, a natural substance involved in your body&#;s construction of genetic material, including DNA (27).

It&#;s easily absorbed and doesn&#;t have the strong laxative effects characteristic of other forms (28).

Early research suggests it may promote heart health due to orotic acid&#;s unique role in the energy production pathways in your heart and blood vessel tissue (28, 29).

As such, it&#;s popular among competitive athletes and fitness enthusiasts, but it may also aid people with heart disease.

One study of 79 people with severe congestive heart failure found that magnesium orotate supplements were significantly more effective for symptom management and survival than a placebo (28).

Yet, this form is significantly more expensive than other magnesium supplements. Based on the limited evidence, its benefits may not justify the cost for many people.

Summary

Magnesium orotate may bolster heart health by improving energy production in your heart and blood vessel tissue.

Should you take a magnesium supplement?

If you don&#;t have low magnesium levels, no evidence suggests a supplement will provide a measurable benefit.

Yet, if you are deficient, obtaining this mineral from whole foods is always the best initial strategy. Magnesium is present in a variety of foods, including (2):

• Legumes: black beans, edamame
• Vegetables: spinach, kale, avocado
• Nuts: almonds, peanuts, cashews
• Whole grains: oatmeal, whole wheat
• Others: dark chocolate

However, a supplement may be worth considering if you cannot get enough magnesium from your diet.

Specific populations may be at a greater risk of deficiency, including older adults and people with type 2 diabetes, digestive disorders, and alcohol dependence (2).

Dosage and possible side effects

The average recommended daily amount of magnesium for adults ranges from 320 mg for females and 420 mg for males (2).

The amounts in different supplement formulations may vary, so check the label to ensure you take the most appropriate dose.

Magnesium supplements are generally considered safe for most people. Once you&#;ve reached adequate levels, your body will excrete any excess in your urine.

However, certain forms or excessive doses may cause mild symptoms like diarrhea or upset stomach.

Although rare, magnesium toxicity can occur. You may be at a greater risk if you have kidney disease or consume very large doses of this mineral. Signs of toxicity include (2):

• nausea
• vomiting
• diarrhea
• muscle weakness
• irregular breathing
• lethargy
• urinary retention

It&#;s always a good idea to consult a healthcare professional before adding dietary supplements.

Summary

Most adults need 320&#;420 mg of magnesium per day. If you&#;re unable to meet your needs from your diet, a supplement may be warranted. They&#;re widely considered safe, but you may want to talk to a health professional before starting.

Read about dietitians&#; picks for the best magnesium supplements.

The bottom line

Magnesium plays a vital role in human health. Low levels are linked to numerous adverse effects, including depression, heart disease, and diabetes.

You may want to consider supplements if you&#;re not getting enough of this mineral in your diet.

Many forms exist, some of which may help relieve heartburn, constipation, and other ailments. If you&#;re unsure which one is right for you, consult a healthcare professional.

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